In this post, we will determine the oxidation numbers in sulfur hexafluoride, SF6.

To determine the oxidation number of an atom(s) in a molecule or an ion, start with the known oxidation numbers and the rules summarized below:



Keep in mind that the summary is zero for neutral molecules and is equal to the charge for ions.

For sulfur hexafluoride, SF6,  the element with a standard oxidation state is fluorine which is -1, and we need to determine the oxidation state of the sulfur. 

Rule 7 – The oxidation of fluorine is –1:

Assign x for the oxidation state of S and set up an equation:

x + 6(-1) = 0, x = +6


Further Reading


More examples of the oxidation state in this multiple-choice quiz:


Oxidation State and Redox Reactions Quiz


Reactions in Aqueous Solutions Quiz

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