## Examples

Calculate the pH of the 0.26 M solution of NH4ClO(Kb NH3 = 1.8 x 10-5).

Ammonium chlorate (NH4ClO3) is the salt of a weak base ammonia (NH3) and a strong acid HClO3, so it yields an acidic solution.

NH3 + HClO3 → NH4ClO3

So, let’s follow what we have discussed earlier and see why it produces an acidic solution.

Dissociate the salt to identify the weak component ion that will react with water:

NH4ClO3 → NH4+ + ClO3

NH4+ is the ion with a weaker component (NH3), so it is going to react with water producing hydronium ion which makes the solution acidic:

NH4+(aq)  + H2O(l) → NH3(aq)  +  H3O+(aq)  (acidic)

The next part is to determine the concentration of H3O+ ions in order to calculate the pH.

We are given the Kb, which measures the base strength and it is based on the reaction of ammonia itself with water:

NH3(aq) + H2O(aq) ⇆ NH4+(aq) + OH(aq)

This equation does not contain H+/H3O+ ions, and we do not know the concentration of ammonia, therefore, we need to determine the Ka.

Ka and Kb can be calculated from one another using the relationship:

Ka · Kb = Kw = 10-14

Rearranging this, we get an expression for Ka:

${K_{\rm{a}}}\; = \,\frac{{{K_{\rm{w}}}}}{{{K_{\rm{b}}}}}\; = \;\frac{{{\rm{1}}{{\rm{0}}^{{\rm{ – 14}}}}}}{{{\rm{1}}{\rm{.8}}\; \times \;{\rm{1}}{{\rm{0}}^{{\rm{ – 5}}}}}}\; = \;{\rm{5}}{\rm{.7 }} \times {\rm{ 1}}{{\rm{0}}^{{\rm{ – 10}}}}$

Once we know the Ka, it is the same procedure as we do when calculating the pH of a weak acid.

We assign x mol/l for ionization and set up an ICE table to determine the [H3O+]:

NH4+(aq)  + H2O(l) → NH3(aq)  +  H3O+(aq)  (acidic)

 [NH4+] [NH3] [H3O+] Initial 0.26 0 0 Change -x +x +x Equil 0.26 – x x x

Next, write the expression for Ka using the equilibrium concentrations in the ICE table:

${K_{{\rm{a}}}}\; = \,\frac{{{\rm{[N}}{{\rm{H}}_{\rm{3}}}{\rm{][}}{{\rm{H}}_{\rm{3}}}{{\rm{O}}^{\rm{ + }}}{\rm{]}}}}{{{\rm{[N}}{{\rm{H}}_{\rm{4}}}^{\rm{ + }}{\rm{]}}}}\; = \;\frac{{{{\rm{x}}^{\rm{2}}}}}{{{\rm{0}}{\rm{.26}}\;{\rm{ – }}\;{\rm{x}}}}\; \approx \;\frac{{{{\rm{x}}^{\rm{2}}}}}{{{\rm{0}}{\rm{.26}}}} = \;{\rm{5}}{\rm{.7 x 1}}{{\rm{0}}^{{\rm{ – 10}}}}$

Therefore, x = 1.2 x 10-5

Check if the approximation was valid:

$\% \, = \;\frac{{1.2\, \times \;{{10}^{ – 5}}}}{{0.26}}\; \times \;100\% \; = \;0.0047\%$

The percentage of hydrolysis is less than 5%, and therefore, the approximation is valid.

The concentration of H3O+ ions is 1.2 x 10-5 M, so the pH is:

pH = -log 1.2 x 10-5 = 4.9

This indicates an acidic solution which is what we expected to have for the solution of NH4ClO3.

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